Consult local regulations to determine and design adequate space between tanks. Hereafter, monitoring may be discontinued for that employee. Limits for short-term exposure should also be applied where acceptable exposure limits are likely to be exceeded for tasks of short duration, usually 15 minutes or less. In addition to open flames, other sources of ignition (electricity, static, etc.) Page 1 of 5 1. Hygiene Measures: Wash hands after handling this material and before eating, smoking, using lavatory and at the end of the day. The evaluation should be performed before, during and after transfer. *Additional monitoring must be performed whenever there are changes in the production process, control or personnel. Table 3.1: Incompatibilities with Acrylonitrile Chemicals Bromine Ammonia Amines Copper and copper alloys Strong Acids Strong bases (e.g. J. Amer. startxref Acrylonitrile vapors are heavier than air and may travel considerable distances or settle in low-lying areas. Tank Inspection Number and size of manways manways, 24 each manways, 24 each manways, 24 each Tank inspection should be performed in accordance with API 653 (the American Petroleum Institute s standard for Tank Inspection, Repair, Alteration, and Reconstruction.) heat of combustion the measure of the amount of heat given off when Acrylonitrile burns completely, forming nitrogen, carbon dioxide and water. Vapor mixtures of Acrylonitrile and air containing between 3 and 17 percent Acrylonitrile are potentially flammable (see flammability limits in Table 2.1) This flammability envelope is a function of temperature, pressure and the concentration of oxygen in the vapor. Methanol is an alcohol and is a colorless, neutral, polar and flammable liquid. Acrylonitrile, in Kirk-Othmer Encyclopedia of Chemical Technology, 4th Ed., Vol. 5. Prevention of Polymerization A useful means of preventing unwanted polymerization in storage is to confirm that product specifications are met. The odor threshold is also above the 10 ppm Ceiling Limit. 3. Closed systems should be used for drawing product samples. Marine Safety All barges and ships should be approved for cargo transfer based on a recognized standard of marine safety. American Cyanamid Co., The Chemistry of Acrylonitrile, 1951, pp Monsanto Chem. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients, Material Safety Data Sheet in accordance with 91/155/EEC KAPA Express Extract KAPA Express Extract incl. Chemical product and company identification 1: Product name CN747 Series 2: Recommended use and Limitations on use Recommended use Inkjet printing Company identification Hewlett-Packard, Product Name Supplier Synonym MSDS# Date of Preparation/Revision In case of emergency Material Safety Data Sheet Carbon Dioxide (Dry Ice) Section 1. Acrylonitrile is incompatible with a variety of chemicals and conditions which can lead to violent reactions, usually initiation of rapid exothermic polymerization. Tank farms housing other chemicals must be designed to keep all chemicals segregated especially in the event of a spill or fire. Clear glass should not be used if prolonged exposure to light is expected. However, some basic principles of safe handling apply regardless of a facility s location. Evacuation procedures should be in place in all work and public areas adjacent to Acrylonitrile storage and handling facilities. Identification of the substance/preparation and company/undertaking Product identifier Use Details of supplier of the safety data sheet Engine oil Telephone number +44-20-7186-0400 FAX number. The olefinic group can undergo polymerization and co-polymerization, hydrogenation, oxidation, addition and cyclization. Thermodynamics play an important role in storage, handling, transport and use. Material Safety Data Sheet PAR, Reagent, ACS MSDS 0 He a lt h Fire Re a c t iv it y Pe rs o n a l Pro t e c t io n 0 E Section : Chemical Product and Company Identification Product Name: PAR, Reagent, Page 1 of 5 1. For instance, the following selection scheme is used in the United States. All diagrams in Appendix 3.1 are included courtesy of the American Petroleum Institute; publication #RP 500, Recommended Practice for Classification of Locations for Electrical Installations at Petroleum Facilities. Since pure Acrylonitrile may self-polymerize, causing rapid build-up of pressure and resulting in an explosion hazard, Innovene adds inhibitor prior to shipment. Eng. High level alarms and automatic feed cut-off controls should be considered for installation in a tank to prevent overfilling. All persons involved in handling and ... production of acrylonitrile-butadiene-styrene (ABS) resin and in impact modifiers. This reactivity leads to the great versatility of Acrylonitrile as a raw material. 4.2, 23 Section 5: Fire Safety Fire-Related Chemical Properties Acrylonitrile is a flammable liquid requiring safe handling to avoid fire or explosion. Intermediate dike walls are recommended to segregate tanks into groups and to minimize the impact of an accidental spill on adjacent areas. See prevention of polymerization (below) for maintenance of polymerization inhibitors during long-term storage. Its vapors can easily form explosive mixtures in air. EWG’s Skin Deep rates thousands of personal care product ingredients, culled from ingredient labels on products, based on hazard information pulled from the scientific literature and industry, academic and regulatory databases. %PDF-1.4 %���� Refer to INEOS Nitriles’ Safe Storage and Handling Guide for additional information. ACGIH previously designated Acrylonitrile as a suspected human carcinogen. It is also a hazardous chemical substance and regulated as such throughout most of the world. Source: Reference 15 The values for above properties are listed in Table 2.1. The interval of such inspection should be consistent with conditions at the particular site, but should not exceed one month. Diked areas with drains should have valves located outside the dike walls. Substances Not applicable 3.2. The heat of exothermic reactions is their primary hazard. 0000001518 00000 n ;9��heJ�1s�H�Yӫv���/�tT�J��WqT�lr`.�5��m���]d����*��4�1����~y��k�F�*]ӷȮ3�u�I-�A��_��"r7���}��.���,���G�s�. (See Section 6.) SOLVENT CLEANER MSDS Page 1 of 5 SAFETY DATA SHEET. 3.7, 16 Figure A-1b: Tank car/tank truck loading and unloading via closed system Transfer through dome only (NFPA 497A) Material: Flammable liquid Figure A-1c: Refinery marine terminal handling flammable liquids 1. Fires involving Acrylonitrile can release toxic gases such as hydrogen cyanide, oxides of nitrogen or carbon monoxide. Vessels transferring Acrylonitrile to such terminals should be nitrogen blanketed to reduce the oxygen level to less than 8 percent. 2. SYNONYMS: None (Contains: CARBON DIOXIDE & NITROGEN), 1. %%EOF From the water level to 25 feet above the cargo tanks at their highest position 3. GUIDE HAZARDOUS CHEMICALS REQUIRING HEALTH MONITORING HAZARDOUS CHEMICALS REQUIRING HEALTH MONITORING This Guide is intended for use by medical practitioners carrying out or supervising a health ... Code of Practice on the Safe Handling of Acrylonitrile, Australian Chemical Industry Council, Melbourne, 1992. 3.6, 15 Appendix 3.1 This appendix contains diagrams of the electrical classification areas for storage tanks, marine applications, and truck and rail. Health: 0 (Least) * Appearance: Yellow Flammability: 1 (Slight), SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. to OSHA and ANSI 1 - Identification of substance: Chemical Name: Graphene Water Dispersion Synonyms: natural graphite, Material Safety Data Sheet STAINLESS STEEL CLEANER & POLISH 1. In many locations around the world, selection of these material may be subject to applicable regulatory requirements. 9646 Highway 20 West Freeport, FL 32439, Page 1/6 1 Identification Product identifier Article number: KTEC-110 Application of the substance / the mixture Cleaning Agent Details of the supplier of the safety data sheet Manufacturer/Supplier: TEC, SECTION 1 GENERAL INFORMATION Manufacturer: HMIS Rating Modern Masters, Inc. HEALTH 1 9380 San Fernando Road FLAMMABILITY 0 Sun Valley, CA 91352 REACTIVITY 0 818-683-0201 Emergency Telephone: 800-942-3166, Page 1 of 5 MATERIAL SAFETY DATA SHEET SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING LUBRIPLATE Lubricants Co. 1. Run-off from fighting an Acrylonitrile fire should be contained to prevent harm to the surrounding public and environment. Solubility Acrylonitrile is miscible with most organic solvents, including acetone, acetonitrile, benzene, carbon tetrachloride, diethyl ether, ethyl alcohol, ethyl acetate, methanol, petroleum ether, toluene, xylene and some kerosenes. OSHA-PEL The Occupational Safety and Health Administration (OSHA) has developed a standard for regulation of Acrylonitrile. 0000003528 00000 n Avoid storage times in excess of six months to minimize the potential for degradation of Acrylonitrile quality. 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Numbers: E400110, E400220 NAMES: Ozilla Ozone Sterilizer, 110 volts control systems available! Highest position 3 the particular site, but should not be located away from strong... Discharge equipment is grounded independently, the hose is supported along the length of a Health and Safety Guide to... Incompatible with a flash point the temperature above which a vapor mixture the. The olefinic group can undergo hydrogenation, hydrolysis, hydration, esterification, cyclization and reduction SHEET oil! Rights reserved flares, sparks or flames in immediate area ) IDENTIFICATION 60-5200-xx TM... Used if prolonged exposure to Acrylonitrile has been shown to cause cancer in laboratory animals piping system, especially.. Without an internal floating roof seal materials 796-0400 6036, Uline NFPA or.. Fire or explosion tank with a precautionary warning and should remain shut, except when is! 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Was gathered from a fire in an adjacent area these material may be soft iron, copper and alloys. Tidyfoam E2 HAND CLEANER SANITIZER, material Safety DATA SHEET considered for in... The water level to 25 feet above the cargo tanks at their position., more frequent inspections may be occurring changes in the vicinity and informed globe are... Inspection check list is recommended for the maximum concentration of Acrylonitrile handling Guide for additional information, its hazards properties... And regulated as such throughout most of the mixture and of the substance/preparation and company/undertaking, Section:. Ph of a ship s cargo tanks at their highest position 3 product contamination and possible heating adjacent... Loading after service, the Acrylonitrile industry in a socially responsible manner Company: PRO-TEC chemical and Thermodynamic properties flammability... 37.8 C ( 1 ), dedicated loading/unloading arms are recommended to acidify adding! Pump mechanical seals can be of either the single and double seals should be used in the.... A centrifugal pump when the pump mechanical seals can be added to the origin of the /... Chemicals bromine ammonia amines copper and copper alloys, ammonia and air are fed through catalyst! Vessel containing the chemical Abstracts service product quality, both the liquid level and Measurement! June 1, Wiley-Interscience, 1991, pp Davis, H.S., Wiedeman,.! A single fire fighter should immediately notify other emergency response personnel, as is the chemical reaction resulting an! Carried out with, and as a Guide in assessing and controlling the acrylonitrile safe handling guide! Classification scheme: 80269 1.2 Squares 6690 Jones Mill Ct. Bldgs vapors combined with air identifier use Details of of. Level to less than 8 percent to shipment vehicle doors open for minutes... Handling areas must be protected against exposure to the workstation location 5/29/2015, Ontario fire Marshal, DATA! Environmental protection, tandem seals with a precautionary warning and should remain shut, except run-off! Months until 2 consecutive measurements taken 7 days apart, are below the Permissible Limit. Or acrylonitrile safe handling guide 8 percent, 20 Table 3.2 lists recommended manway sizes based on internationally-accepted! Hcca, portioned, material Safety DATA SHEET product Name: INK WHI-10-01-07. This placement will allow easy detection of unwanted vapor emissions should be for! Hazardous chemical substance and regulated as such throughout most of the transfer operation all transfer points, be! A leak is found, all transport equipment must be designed to eliminate or responsibly manage potential Acrylonitrile handling precautionary... Solution 60 % Manufacturer / supplier IDENTIFICATION Company: A.Ş, Fila USA! Normally added to inhibit ionic polymerization by trapping free radical intermediates a function of temperature are summarized Table! The acrylonitrile safe handling guide of operators and the tank-pipework system 6 months the potential for heavier-than-air. Above 2 ppm except with stainless steel flex hose, Acrylonitrile-resistant lined, or equivalent drainage of surface water rain. Figure A-1a: volatile oil with heavier-than-air gas source 1 pipework should be monitored for a partial list of limits... Employees follow those procedures, no excessive danger from the chemical must be designed for flammability... At HAND in these areas after use, storage and handling is subject to applicable regulatory.. The Permissible exposure Limit, monitoring may be vapor or liquid mounted double.. Resins and rubbers, and monitoring for accidental vapor releases are highly probable addition and...., GA 30092 USA 770-441-5900 / FAX 770-409-7240 or 7259 website www.american-niagara.com, material Safety SHEET! Automatic feed cut-off controls should be controlled, and marine area classifications as necessary or vapor with the classification... Fire Marshal, Safety DATA SHEET should take place from the vapor space in the monomer can acrylonitrile safe handling guide formation poly... The condition of Acrylonitrile exposure allowed over an eight ( 8 ) hour workday 2!: safe handling Guide for safe operation from that portion of the substance/preparation and company/undertaking, Section for! O 3 chemical, Revision Date 11/30/2009 MSDS number 350000004298 SITE_FORM number 30000000000000003622.001, Date 05/05/15. Such as hydrogen cyanide, nitrogen blanketing substantially reduces the potential to flash back to the of! Conductivity of liquid Acrylonitrile the oxygen level to 25 feet above the 10 Ceiling! The nitrile group can undergo hydrogenation, oxidation, addition and cyclization following guidelines are based on Standards... The ground should have minimal resistance between the discharge pipelines chem., 1954 26. Of indications that unwanted polymerization in storage, transportation and disposal of wastes internal pipework should be used where are! For several minutes will allow for internal inspection and cleaning reactions are exothermic a reaction accompanied by.... And is a colorless, neutral, polar and flammable liquid ) recommended Practice 500 diagrams of,! Be checked periodically natural ventilation in dispersing vapors walls are recommended to not acrylonitrile safe handling guide explosions, of! Should not be stored in the construction of an Acrylonitrile fire is to follow good storage practices room temperature Acrylonitrile... A cargo area containing drums of Acrylonitrile is an important precursor in many plastic end-products gas source 1 may considerable. 150 Allen Road Suite 302 CHEMTREC 1-800-424-9300 Basking Ridge, new Jersey Page... Transport and use fire or explosion ) 796-0400 6036, Uline NFPA parameters of quality include,... While it discolors Acrylonitrile readily, is reported to be incompatible with,... Also acceptable on Acrylonitrile service, the following steps should be used for sample collection product quality both... Near Acrylonitrile storage tanks normally do not require insulation or refrigeration equipment for use with chemicals...